Bis(amino)phosphines Derived From N-phenylpiperazine and N-ethylpiperazine: Synthesis, Oxidation Reactions, and Molybdenum Complexes

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dc.contributor.authorSarioz, Ozlem
dc.contributor.authorOznergiz, Sena
dc.contributor.authorKandemirli, Fatma
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2013
dc.departmentNiğde ÖHÜ
dc.description.abstractFunctionalized bis(amino)phosphines that are the type PhP(NR2)2 (1,2) have been synthesized by treating PhPCl2 with N-phenylpiperazine or N-ethylpiperazine. Ligands react with aqueous hydrogen peroxide, elemental sulfur, or selenium to give the corresponding chalcogenides (38) in good yield. The molybdenum complexes of the bis(amino)phosphines (9,10) have been obtained. All of the compounds obtained in good yields and they were characterized by IR, NMR, microanalysis, and also quantum chemical calculations such as HOMO-LUMO energies, Mulliken charges, and dipole moment for compounds 18 and complex 9 were carried out by using B3LYP/6-31G(d,p), a version of the DFT method with standard Gaussian 09 software package program.
dc.description.sponsorshipResearch Foundation of The University of Nigde (NUAF)
dc.description.sponsorshipThe authors are grateful to Research Foundation of The University of Nigde (NUAF) for financial support.
dc.identifier.doi10.1080/15533174.2012.740709
dc.identifier.endpage195
dc.identifier.issn1553-3174
dc.identifier.issue2
dc.identifier.scopus2-s2.0-84872046051
dc.identifier.scopusqualityN/A
dc.identifier.startpage185
dc.identifier.urihttps://dx.doi.org/10.1080/15533174.2012.740709
dc.identifier.urihttps://hdl.handle.net/11480/4434
dc.identifier.volume43
dc.identifier.wosWOS:000312984600013
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherTAYLOR & FRANCIS INC
dc.relation.ispartofSYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectaminophosphines
dc.subjectoxidation
dc.subjectquantum chemical calculations
dc.subjectsynthesis
dc.titleBis(amino)phosphines Derived From N-phenylpiperazine and N-ethylpiperazine: Synthesis, Oxidation Reactions, and Molybdenum Complexes
dc.typeArticle

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