Karboksilli diaminoetil bağlı PVC'nin bazı geçiş metalleri komplekslerinin sentezi
Küçük Resim Yok
Tarih
2003
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Niğde Üniversitesi
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
ÖZET KARBOKSİLLİ DİAMİNOETİL BAĞLI PVC NİN BAZI GEÇİŞ METALLERİYLE KOMPLEKSLERİNİN SENTEZİ KURT, Gülşah Niğde Üniversitesi Fen Bilimleri Enstitüsü Kimya Ana Bilim Dab Danışman: Doç. Dr. Bedrettin MERCİMEK Eylül 2003, 50 sayfa Poli(vinil klorür) (PVC)' nin etilendiamin ve bromoasetikasit ile modifiyesiyle karboksillidiaminoetil bağlı PVC ligandı sentezlenmiş ve bu ligandın Co(II), Ni(II), Cu(II) metalleri ile yapmış olduğu kompleksler sentezlenmiştir. Bu komplekslerin yapılan Magnetik susseptibilite, elementel ve İR spektral analiz teknikleri ile tayin edilmeye çalışılmıştır. Anahtar sözcüklenEtüendiamin, nikel(II), kobalt(II), bakır(II), kompleks, PVC in
SUMMARY SYNTHESIS OF SOME TRANSITION METAL COMPLEXES OF POLY(VİNYL CHLORIDE) BOUND CARBOXYLATED DİAMİNOETHYL KURT, Gülşah Niğde University Graduate School of Natural and Applied Sciences Department of Chemistry Supervisor : Doç.Dr. Bedrettin MERCİMEK September 2003, 50 pages Poly(vinyl chloride)(PVC) has been modified with diaminoethane, bromoacetic acid as PVC-CDAE, which has been characterized by spektroscopic and elemental analyses. PVC-CDAE has further been reacted with alcoholic solutions of Co(II), Ni(II), and Cu(II) to form the intensely colored PVC-CDAE-M(II) complexes. The structures of these complexes have been analyzed by elemental, Magnetic Susceptibility and IR spectral analyses. Key words: Ethylenediamine, PVC, nickel(II), copper(II), cobalt(II), complexes IV
SUMMARY SYNTHESIS OF SOME TRANSITION METAL COMPLEXES OF POLY(VİNYL CHLORIDE) BOUND CARBOXYLATED DİAMİNOETHYL KURT, Gülşah Niğde University Graduate School of Natural and Applied Sciences Department of Chemistry Supervisor : Doç.Dr. Bedrettin MERCİMEK September 2003, 50 pages Poly(vinyl chloride)(PVC) has been modified with diaminoethane, bromoacetic acid as PVC-CDAE, which has been characterized by spektroscopic and elemental analyses. PVC-CDAE has further been reacted with alcoholic solutions of Co(II), Ni(II), and Cu(II) to form the intensely colored PVC-CDAE-M(II) complexes. The structures of these complexes have been analyzed by elemental, Magnetic Susceptibility and IR spectral analyses. Key words: Ethylenediamine, PVC, nickel(II), copper(II), cobalt(II), complexes IV
Açıklama
Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalı
Anahtar Kelimeler
Kimya, Chemistry
