Synthesis, characterization, and histological activity of novel polydentate azo ligands and their cobalt(II), copper(II) and nickel(II) complexes
Küçük Resim Yok
Tarih
2008
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
SPRINGER
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
We describe the synthesis and characterization of two novel azo ligands, 4,5-dihydroxy-3,6-bis(2-hydroxyphenylazo)-2,7 naphthalene disulfonic acid (H(2)L) and 4,5-dihydroxy-3,6-bis(2-hydroxy-4-sulfophenylazo)-2,7-naphthalenedisulfonic acid (H(2)L(1)). The Cu(II), Ni(II), and Co(II) complexes of these ligands were prepared and characterized by infrared, UV-Vis, (1)H- and (13)C-NMR spectra, atomic absorption spectroscopy, mass spectrometry, elemental analyses, thermogravimetric analysis, conductivity, cyclic voltammetry, and magnetic measurements. The results suggest that the complexes have a 2:1 (metal:ligand) molar ratio, involving binuclear azo ligands with an ONO donor set. Metal ion uptake studies were conducted with a batch technique. Preliminary histological studies were also made. The results indicate that the azo ligands have high thermal stability, good metal extraction capacity, and favorable dying properties with certain tissues.
Açıklama
Anahtar Kelimeler
Kaynak
TRANSITION METAL CHEMISTRY
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
33
Sayı
5
