Synthesis, characterization, and histological activity of novel polydentate azo ligands and their cobalt(II), copper(II) and nickel(II) complexes

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dc.contributor.authorTuncel, Mehmet
dc.contributor.authorKahyaoglu, Huelya
dc.contributor.authorCakir, Mehmet
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2008
dc.departmentNiğde ÖHÜ
dc.description.abstractWe describe the synthesis and characterization of two novel azo ligands, 4,5-dihydroxy-3,6-bis(2-hydroxyphenylazo)-2,7 naphthalene disulfonic acid (H(2)L) and 4,5-dihydroxy-3,6-bis(2-hydroxy-4-sulfophenylazo)-2,7-naphthalenedisulfonic acid (H(2)L(1)). The Cu(II), Ni(II), and Co(II) complexes of these ligands were prepared and characterized by infrared, UV-Vis, (1)H- and (13)C-NMR spectra, atomic absorption spectroscopy, mass spectrometry, elemental analyses, thermogravimetric analysis, conductivity, cyclic voltammetry, and magnetic measurements. The results suggest that the complexes have a 2:1 (metal:ligand) molar ratio, involving binuclear azo ligands with an ONO donor set. Metal ion uptake studies were conducted with a batch technique. Preliminary histological studies were also made. The results indicate that the azo ligands have high thermal stability, good metal extraction capacity, and favorable dying properties with certain tissues.
dc.identifier.doi10.1007/s11243-008-9087-6
dc.identifier.endpage613
dc.identifier.issn0340-4285
dc.identifier.issue5
dc.identifier.scopus2-s2.0-45849087316
dc.identifier.scopusqualityQ2
dc.identifier.startpage605
dc.identifier.urihttps://dx.doi.org/10.1007/s11243-008-9087-6
dc.identifier.urihttps://hdl.handle.net/11480/5218
dc.identifier.volume33
dc.identifier.wosWOS:000256915300012
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherSPRINGER
dc.relation.ispartofTRANSITION METAL CHEMISTRY
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.titleSynthesis, characterization, and histological activity of novel polydentate azo ligands and their cobalt(II), copper(II) and nickel(II) complexes
dc.typeArticle

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