Floroiyonofor grubu içeren komplekslerin sentezi
Yükleniyor...
Tarih
2019
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Niğde Ömer Halisdemir Üniversitesi / Fen Bilimleri Enstitüsü
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Bu çalışmada; 2,4-dihidroksibenzaldehit bileşiğinden çıkılarak N,N'-Bis(2,4-dihidroksibenziliden)fenilen-1,2-diamin Schiff bazı sentezlendi. Schiff bazının 2-kloro-N-(naftalen-1-il)asetamit floroiyonofor grubu ile reaksiyonundan yeni bir ligand ve bu ligandın Co(II), Ni(II), Cu(II), Zn(II), Hg(II) kompleksleri sentezlendi. Elde edilen bileşiklerin yapıları FT-IR, elementel analiz, 1H-NMR, UV-Vis, SEM-EDX, ve TGA yöntemleri ile aydınlatıldı. Florometri ile ligand ve komplekslerin floresans davranışları incelendi. Manyetik süssebtibilite ile Co(II), Ni(II) ve Cu(II) komplekslerinin geometrileri belirlendi.
In this study; N,N'-Bis(2,4-dihydroxybenzylidene)phenylene-1,2-diamine Schiff base was synthesized from 2,4-dihydroxybenzaldehyde. A new ligand from the reaction of Schiff base with 2-chloro-N-(naphthalen-1-yl)acetamide fluoroionophore group and its ligand Co(II), Ni(II), Cu(II), Zn(II), Hg(II) complexes were synthesized. The structures of the compounds obtained were elucidated by FT-IR, elemental analysis, 1H-NMR, UV-Vis, SEM-EDX, and TGA methods. Fluorescence behavior of ligands and complexes was investigated by fluorometry. Magnetic susceptibility of Co(II), Ni(II) and Cu(II) complexes were determined.
In this study; N,N'-Bis(2,4-dihydroxybenzylidene)phenylene-1,2-diamine Schiff base was synthesized from 2,4-dihydroxybenzaldehyde. A new ligand from the reaction of Schiff base with 2-chloro-N-(naphthalen-1-yl)acetamide fluoroionophore group and its ligand Co(II), Ni(II), Cu(II), Zn(II), Hg(II) complexes were synthesized. The structures of the compounds obtained were elucidated by FT-IR, elemental analysis, 1H-NMR, UV-Vis, SEM-EDX, and TGA methods. Fluorescence behavior of ligands and complexes was investigated by fluorometry. Magnetic susceptibility of Co(II), Ni(II) and Cu(II) complexes were determined.
Açıklama
Anahtar Kelimeler
Schiff bazı, Floroiyonofor, Metal kompleksler, 2-kloro-N-(naftalen-1-il)asetamit, Schiff base, Fluoroionophore, Metal complexes, 2-chloro-N-(naphthalene-1-il)acetamide
Kaynak
WoS Q Değeri
Scopus Q Değeri
Cilt
Sayı
Künye
Yıldırım, S. (2019). Floroiyonofor grubu içeren komplekslerin sentezi. (Yüksek Lisans Tezi) Niğde Ömer Halisdemir Üniversitesi, Fen Bilimleri Enstitüsü, Niğde
