N2O tipi ligand ile metal komplekslerinin sentezi ve yapılarının aydınlatılması
Küçük Resim Yok
Tarih
2010
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Niğde Üniversitesi
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Bu çalışmada, 4-4'-Diamino-bibenzyl kullanıldı ve farklı bir aldehit olan ß-hidroksi-1-naftaldehit ile reaksiyonundan yeni bir ligand 1,1'-(4-4'-(ethane-1,2-diyl)bis(4,1-phenylene))bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)dinaphthalen-2-ol (HL)schiff bazı elde edilmiştir.Bir ligandın Ni(II), Zn(II) ve Cu(II) asetat tuzları ile 3 (üç) metal kompleksi sentezlendi.Sentezlenen yeni bileşiklerin yapıları; FT-IR, Elementel Analiz, 1H-NMR, 13C-NMR,UV yöntemleri ve SEM ile aydınlatıldı.1,1'-(4-4'-(ethane-1,2-diyl)bis(4,1-phenylene))bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)dinaphthalen-2-ol ligandı ve bunun 3 (üç) yeni metal kompleksi sentezlenerekizole edilmiştir.
In this study, 4-4'-Diamino-bibenzyl was used and a new ligand1,1'-(4-4'-(ethane-1,2-diyl)bis(4,1-phenylene))bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)dinaphthalen-2-ol (HL) schiff base was obtained from the reaction with ß-hidroksi-1-naftaldehit, which is a different aldehyde.Ni(II), Zn(II) ve Cu(II) acetates of this ligand were synthesized with 3(three) metalcomplexes. The structures of the new compounds which were synthesized were lightedwith the help of FT-IR, Elementel Analiz, 1H-NMR, 13C-NMR, UV methods and SEM.1,1'-(4-4'-(ethane-1,2-diyl)bis(4,1-phenylene))bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)dinaphthalen-2-ol ligand and ve its 3 (three) new metal complexes wereisolated by synthesizing.
In this study, 4-4'-Diamino-bibenzyl was used and a new ligand1,1'-(4-4'-(ethane-1,2-diyl)bis(4,1-phenylene))bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)dinaphthalen-2-ol (HL) schiff base was obtained from the reaction with ß-hidroksi-1-naftaldehit, which is a different aldehyde.Ni(II), Zn(II) ve Cu(II) acetates of this ligand were synthesized with 3(three) metalcomplexes. The structures of the new compounds which were synthesized were lightedwith the help of FT-IR, Elementel Analiz, 1H-NMR, 13C-NMR, UV methods and SEM.1,1'-(4-4'-(ethane-1,2-diyl)bis(4,1-phenylene))bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)dinaphthalen-2-ol ligand and ve its 3 (three) new metal complexes wereisolated by synthesizing.
Açıklama
Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalı
Anahtar Kelimeler
Kimya, Chemistry
